Structural Formula Vector Image
Title: Solanone
CAS Registry Number: 1937-54-8
CAS Name: (5S,6E)-8-Methyl-5-(1-methylethyl)-6,8-nonadien-2-one
Additional Names: L-(+)-2-methyl-5-isopropyl-1,3-nonadien-8-one
Molecular Formula: C13H22O
Molecular Weight: 194.31
Percent Composition: C 80.36%, H 11.41%, O 8.23%
Literature References: Stereochemically unique terpene. Isoln from tobacco, structure and synthesis: Johnson, Nicholson J. Org. Chem. 30, 2918 (1965). Stereoselective synthesis: A. Kohda, T. Sato, Chem. Commun. 1981, 951.
Properties: Liquid. bp1 60°. nD20 1.4755. d420 0.870. [a]D23 +13.6° (neat). uv max (ethanal and hexane): 230 nm (log e 4.07).
Boiling point: bp1 60°
Optical Rotation: [a]D23 +13.6° (neat)
Index of refraction: nD20 1.4755
Absorption maximum: uv max (ethanal and hexane): 230 nm (log e 4.07)
Density: d420 0.870

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