Sodium Hypochlorite Solution
NaClO 74.44

Hypochlorous acid, sodium salt.
Sodium hypochlorite [7681-52-9].
» Sodium Hypochlorite Solution contains not less than 4.0 percent and not more than 6.0 percent, by weight, of NaClO.
[Caution—This Solution is not suitable for application to wounds. ]
Packaging and storage— Preserve in tight, light-resistant containers, at a temperature not exceeding 25.
Identification—
A: The Solution at first colors red litmus blue and then bleaches it.
B: The addition of 3 N hydrochloric acid to the Solution causes an evolution of chlorine.
C: The solution obtained in Identification test B responds to the flame test for Sodium 191.
Assay— Weigh accurately, in a glass-stoppered flask, about 3 mL of Solution, and dilute it with 50 mL of water. Add 2 g of potassium iodide and 10 mL of 6 N acetic acid, and titrate the liberated iodine with 0.1 N sodium thiosulfate VS, adding 3 mL of starch TS as the endpoint is approached. Perform a blank determination, and make any necessary correction. Each mL of 0.1 N sodium thiosulfate is equivalent to 3.722 mg of NaClO.
Auxiliary Information— Please check for your question in the FAQs before contacting USP.
Topic/Question Contact Expert Committee
Monograph Ahalya Wise, M.S.
Senior Scientific Liaison
1-301-816-8161
(SM12010) Monographs - Small Molecules 1
USP35–NF30 Page 4662